2 films match D.E.B.S.

Recruited by the U.S. Government for their unique ability to lie, cheat and fight, Amy, Max, Janet and Dominique join an underground academy of secret agents known only as D.E.B.S. These crime fighting hotties set out to save the world and keep their lipstick perfectly applied while doing so. (Sony)

A quartet of girls from a prep high school are recruited by a secret paramilitary academy to conduct cloak-and-dagger missions. (imdb)